While studying cathode rays in 1895, Wilhelm Röntgen discovered a new form of penetrating radiation. He named it with X, the symbol for an unknown quantity, and produced a famous image of a hand.
X-rays pass through some materials, and differences in absorption by tissues create contrast in images. They later found wide use in medicine and materials research.
Pre-Röntgen observations and research
X-rays were originally noticed in science as a type of unidentified radiation emanating from discharge tubes by experimenters investigating cathode rays produced by such tubes, which are energetic electron beams that were first observed in 1869. Early researchers noticed effects that were attributable to them in many of the early Crookes tubes (invented around 1875). Crookes tubes created free electrons by ionization of the residual air in the tube by a high DC voltage of anywhere between a few kilovolts and 100 kV. This voltage accelerated the electrons coming from the cathode to a high enough velocity that they created X-rays when they struck the anode or the glass wall of the tube.
The earliest experimenter thought to have (unknowingly) produced X-rays was William Morgan. In 1785, he presented a paper to the Royal Society of London describing the effects of passing electrical currents through a partially evacuated glass tube, producing a glow created by X-rays. This work was further explored by Humphry Davy and his assistant Michael Faraday.
Discovery by Röntgen
On 8 November 1895, German physics professor Wilhelm Röntgen discovered X-rays while experimenting with Lenard tubes and Crookes tubes and began studying them. He wrote an initial report "On a new kind of ray: A preliminary communication" and on 28 December 1895, submitted it to Würzburg's Physical-Medical Society journal. This was the first paper written on X-rays. Röntgen referred to the radiation as "X", to indicate that it was an unknown type of radiation. Some early texts refer to them as Chi-rays, having interpreted "X" as the uppercase Greek letter Chi, Χ.
There are conflicting accounts of his discovery because Röntgen had his lab notes burned after his death, but this is a likely reconstruction by his biographers: Röntgen was investigating cathode rays from a Crookes tube which he had wrapped in black cardboard so that the visible light from the tube would not interfere, using a fluorescent screen painted with barium platinocyanide. He noticed a faint green glow from the screen, about 1 meter (3.3 ft) away. Röntgen realized some invisible rays coming from the tube were passing through the cardboard to make the screen glow. He found they could also pass through books and papers on his desk. Röntgen threw himself into investigating these unknown rays systematically. Two months after his initial discovery, he published his paper.
Röntgen discovered their medical use when he made a picture of his wife Anna Bertha Ludwig's hand on a photographic plate formed due to X-rays. The photograph of his wife's hand was the first photograph of a human body part using X-rays. When she saw the picture, she said "I have seen my death."
The discovery of X-rays generated significant interest. Röntgen's biographer Otto Glasser estimated that, in 1896 alone, as many as 49 essays and 1044 articles about the new rays were published. This was probably a conservative estimate, if one considers that nearly every paper around the world extensively reported about the new discovery, with a magazine such as Science dedicating as many as 23 articles to it in that year alone. Sensationalist reactions to the new discovery included publications linking the new kind of rays to occult and paranormal theories, such as telepathy.
The name X-rays stuck, although (over Röntgen's great objections) many of his colleagues suggested calling them Röntgen rays. They are still referred to as such in many languages, including German, Hungarian, Ukrainian, Danish, Polish, Czech, Bulgarian, Swedish, Finnish, Portuguese, Estonian, Slovak, Slovenian, Turkish, Russian, Latvian, Lithuanian, Albanian, Japanese, Dutch, Georgian, Hebrew, Icelandic, and Norwegian.